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Beilstein J. Org. Chem. 2010, 6, 978–983, doi:10.3762/bjoc.6.110
Graphical Abstract
Scheme 1: Proposed aziridinyl anion induced N- to C-phosphonyl migration.
Scheme 2: Selected previously observed N- to C-phosphorous migrations [17,18,21].
Scheme 3: Partial N- to C-migration with N-diphenylphosphinylaziridine 10 [24].
Scheme 4: Synthesis and rearrangement of aziridine 1a.
Figure 1: Aziridines 1h–j.
Scheme 5: Synthesis and rearrangement of aziridine (S)-1k.
Scheme 6: Hydrogenolysis of aziridinylphosphonate (–)-3k.